The Mail app included with Windows 8 only supports IMAP, Exchange, Hotmail/Outlook.com, and Gmail accounts. Mail offers POP3 as an option when setting up the account – but if you select POP3, you’ll be informed that Mail doesn’t support POP.
To use the Mail app with a POP3 email account, giving you features such as live-tile email notifications and a touch-friendly interface for reading your email, there’s a trick you can use.